Chemistry: why nitric acid is more acidic than nitrous

Tutoring chemistry, the concept of acid strength is important. The tutor explains why nitric acid is more acidic that nitrous.

Nitric acid (HNO3) and nitrous acid (HNO2) both have N as the central atom, and share the structure H-O-N….However, nitric acid has an extra oxygen on the other side of N, which causes more electron drain from the N atom. The N atom, in turn, pulls electron density from the O between it and the H. With less electron availability, the O adjacent to H in HNO3 can less effectively attract H+, so loses it more readily than does HNO2.

Source:

Mortimer, Charles E. Chemistry, sixth ed. Belmont: Wadsworth, 1986.

Jack of Oracle Tutoring by Jack and Diane, Campbell River, BC.

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