Chemistry: naming inorganic acids

Tutoring chemistry, you encounter acids.  The chemistry tutor shares some observations about how to name them.

New students to the acid-and-base topic hear names like hydrochloric acid, nitric acid, and sulphurous acid.  Recently I was asked why some are hydro-, while others are -ic or -ous?

Before answering the questions about naming, I should introduce the generic formula of an inorganic acid.  It goes like this:

HnAnion,

where n, the number of H atoms, is equal to the negative charge on the anion. (An anion is a negatively charged ion.)

How to name the acid is determined by its anion, according to these three rules:

  1. If the anion is a single atom, such as S or Cl, the acid is a hydro- acid, with -ic following the atom’s name.  Examples:  H2S is hydrosulphuric acid; HCl is hydrochloric acid.
  2. If the anion is an -ate, such as nitrate, the acid is -ic.  For instance, HNO3 is nitric acid, since its anion, NO3, is nitrate. Similarly, H2SO4 is sulphuric acid; you recognize its anion, SO4, as sulphate.
  3. If the anion is an -ite, such as nitrite, the acid is -ous.  Therefore, HNO2 is nitrous acid, since its anion, NO2, is nitrite. H2SO3 is sulphurous acid; note its anion, SO3, is sulphite.

These hints should answer most questions about inorganic acid nomenclature at the high school level:)

Source: Mortimer, Charles E. Chemistry, sixth edition. Belmont, California:    Wadsworth Publishing Company, 1986.

Jack of Oracle Tutoring by Jack and Diane, Campbell River, BC.

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