Thermodynamics: first law, with compression of a gas
The tutor begins about thermodynamics with the example of compressing a gas.
Thermodynamics is the analysis of energy – particularly, how it moves and/or changes form. The First Law of Thermodynamics is the Law of Conservation of Energy: Energy cannot be created or destroyed, but merely moves or changes form.
Let’s imagine a system that has internal energy U. Then U can change only by work or heat (Δ means change):
ΔU = q + w,
q= heat,
w=work.
If q is negative, heat is leaving the system; if w is negative, the system is doing work against its environment.
The internal energy of an ideal gas is directly proportional to its temperature: specifically,
U = 1.5nRT, where
n= moles of gas present
R=8.315J/(K*mol), which is the gas constant
T=temperature in Kelvin
As a gas is compressed, work is done to it (so w is positive). Let’s imagine rapid compression that does not allow time for heat to escape, so q=0. Then according to
ΔU = q + w,
U must increase. Since
U = 1.5nRT
the temperature of the (ideal) gas must rise with compression.
The rise of temperature during compression enables diesel engines and refrigerators to work.
Source:
Giancoli, Douglas C. Physics, 5th ed. New Jersey: Prentice Hall, 1998.
Jack of Oracle Tutoring by Jack and Diane, Campbell River, BC.
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